https://ogma.newcastle.edu.au/vital/access/ /manager/Index ${session.getAttribute("locale")} 5 Cytotoxicity of a series of norcantharidin-inspired tetrahydroepoxyisoindole carboxamides https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:27267 Wed 17 Nov 2021 16:32:46 AEDT ]]> The catalyzed conversion of methane to value-added products https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:37280 4) to organic oxygenates utilizing heterogeneous and homogeneous processes conducted in the gaseous or liquid phase is reviewed. The most active catalytic systems are examined in terms of rates, longevity, and reaction mechanisms. Despite significant effort, the successful heterogeneous mimicking of selective CH4 oxidation performed in an enzymatic system (methane monooxygenase) is still elusive. Under mild reaction conditions, the reaction is too slow, and under harsh conditions, total oxidation prevails. Thus, of particular interest herein is the assessment of oxidation at intermediate temperatures to 1) reduce total oxidation and 2) obtain sufficient concentration of activated oxygen and CH4 species. Important operational parameters such as reaction conditions, catalyst preparation methods, and cofeeding of chemicals, which significantly affect the yield of desired products, are discussed. One particular system that is successful is the catalytic conversion of CH4 to methanol under mild conditions using nitrous oxide (N2O) with Fe-based catalysts or oxygen (O2) with Cu-based catalysts. Special attention is paid to the controversy related to the identification of active sites, where the oxygen species suitable for CH4 oxidation are purportedly formed.]]> Wed 16 Sep 2020 18:36:19 AEST ]]> Effect of protic ionic liquid and surfactant structure on partitioning of polyoxyethylene non-ionic surfactants https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:18762 Wed 11 Apr 2018 14:54:37 AEST ]]> General principles of electrochemistry https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:18438 Thu 25 Jun 2015 13:41:18 AEST ]]> Rare-Earth Doped Iron Oxide Nanostructures for Cancer Theranostics: Magnetic Hyperthermia and Magnetic Resonance Imaging https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:46251 Thu 23 Mar 2023 09:46:38 AEDT ]]> Locomotion with a twist: Aquatic beetle walks upside down on the underside of the water's surface https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:48872 Thu 13 Apr 2023 12:40:30 AEST ]]> Lattice Monte Carlo and experimental analyses of the thermal conductivity of random-shaped cellular aluminum https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:7263 Sat 24 Mar 2018 08:33:49 AEDT ]]> Chute performance and design for rapid flow conditions https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:1591 Sat 24 Mar 2018 08:30:30 AEDT ]]> Generation of nanoparticle, atomic-cluster, and single-atom cobalt catalysts from zeolitic imidazole frameworks by spatial isolation and their use in zinc-air batteries https://ogma.newcastle.edu.au/vital/access/ /manager/Repository/uon:36381 2 , which was attributed to the high reactivity and stability of isolated single Co atoms. Our findings open up a new avenue to regulate the metal particle size and catalytic performance of MOF derivatives.]]> Fri 03 Apr 2020 16:59:31 AEDT ]]>